Death toll in Tianjin explosions reaches 112; more than 90 still missing

Story highlights

Angry families storm a news conference demanding to know about missing relatives

Authorities need to learn from 'extremely profound' lessons, Chinese President says

Tianjin, China CNN  — 

Crews searched for an unknown number of civilians and soldiers Saturday who are believed trapped by multiple explosions that killed at least 112 people this week in this eastern Chinese city.

As of Sunday morning, more than 50 people have been rescued in Tianjin, city government spokesman Gong Jiansheng said. They include a 19-year-old firefighter who lay on the ground for hours with burns and a cracked skull until he was found, officials said.

Relatives of some of the 95 people missing, mainly firefighters, stormed an official news conference demanding to know the whereabouts of their loved ones. Families wrote the names of missing people on posters lining a street outside a temporary shelter near the rescue site.

On Saturday, fires sent plumes of black smoke skyward near where explosions devastated a chemical warehouse in Tianjin on Wednesday.

But officials denied news reports that an evacuation order had been immediately issued for everyone within 1.8 miles (3 kilometers), with Gong calling the reports “false information.”

The Beijing News, citing the People’s Armed Police Force, had reported the evacuation order. CNN has reported that at least one disaster recovery shelter is located within the reported evacuation zone.

However, photographs made it appear that vehicles in a parking lot had caught fire rather than new explosions having taken place at the warehouse, as the Xinhua news agency had reported.

‘Lessons paid for with blood’

Chinese President Xi Jinping said Saturday that the Tianjin blasts and other recent accidents exposed severe problems in workplace safety.

The president also “urged authorities to learn from the ‘extremely profound’ lessons paid for with blood” in the Tianjin explosions, Xinhua said.

Xi is demanding improvements to workplace safety, the agency added.

The first blasts on Wednesday, one of which carried the equivalent of more than 20 tons of TNT, left more than 700 people injured and thousands homeless, officials said. A man around 40 years old was reported to have been rescued from the site on Saturday.

While flames are largely extinguished, residents are worried about lingering contamination after explosive fires at a chemical warehouse devastated part of the port city of Tianjin.

“I asked my in-laws to take my daughter home, I don’t want them to stay here,” migrant worker Tian Binyan told CNN. “I’m worried. I heard it’s going to rain later and that would make the air toxic.”

She was among the 6,000 or so displaced by the fire and explosions that rocked the port Wednesday night, sending huge fireballs and plumes of smoke into the air.

What chemicals did the warehouse store?

Tianjin officials say they are unable to give a detailed list of exactly what chemicals were being stored at the warehouse.

Gao Huaiyou, the deputy director of the city’s Work Safety Administration, said Friday the warehouse was only a temporary storage facility. Materials were kept there briefly when they arrived at the port and before they were transported elsewhere.

Tianjin map

The warehouse site was destroyed by the explosions, he told reporters at a news conference, and managers of the facility have provided “insufficient information” about what was stored there.

Sodium cyanide, a highly toxic chemical that can rapidly kill humans exposed to it, was one of the materials, Gao said.

The environmental group Greenpeace, citing a local monitoring station, said it believed other dangerous chemicals stored at the site included toluene diisocyanate and calcium carbide.

Gao said further investigation, including checks of customs records, would be needed to try to establish the types and amounts of the chemicals at the warehouse.

What is the environmental toll?

Chinese officials have sent chemical and biological experts to the scene, and some 1,000 firefighters are still at the ravaged site, pouring foam and sand on lingering hotspots, according to authorities.

Wen Wurui, Tianjin’s environment protection chief, said Thursday that some chemical levels in the area were higher than normal but that they wouldn’t be dangerous to humans unless someone is exposed to them for long periods.

And environmental officials said that they’ve found nothing unusual in the waters off Tianjin, state media reported.

Still, the worries persist.

Liu Yue, a 25-year-old who lives about 4 kilometers (2.48 miles) from the blast site said she and others were taking precautions against possible contamination.

“I’ve told my parents not to drink tap water,” she said.

Firefighters’ families in search of answers turned away

What caused the blasts?

Fire officials say hazardous chemicals stored at the warehouse were ignited by fire. But the cause of the fire has yet to be determined.

Executives from Rui Hai International Logistics Co., the company that owned the warehouse, have been taken into custody, state media reported Thursday.

Lei Jinde, an official from the Chinese Public Security Ministry’s firefighting bureau, told, a Shanghai-based newspaper, in a telephone interview that the first team of firefighters used water in an attempt to contain the fire. It was necessary to cool the blaze, he said, according to a CNN translation.

But water isn’t the best fire suppressant for some chemicals.

Calcium carbide reacts with water to form acetylene, which can catch fire.

“We knew there was calcium carbide inside (the warehouse), but no one had knowledge if it was exploding or on fire,” Lei said. “It’s not that the firefighters were stupid that they would still use water (to put out) after knowing there was calcium carbide. I didn’t mean that. We absolutely can’t say it was wrong to use water.”

Authorities in Tianjin appeared to have been concerned recently about the handling of hazardous materials at the port.

A notice posted by the Tianjin Administration of Work Safety on its website last week said city officials held a meeting with executives of more than 20 companies that handle dangerous chemicals at the port.

How many lives did the explosions claim?

At least 85 are known dead, among them 21 firefighters, but many are still missing, including dozens of employees of the company that owed the warehouse, according to Xinhua.

One firefighter was rescued Friday from the rubble, Xinhua reported.

One of killed firefighters was recovered at the rescue scene, and about a dozen other firefighters flanked and stood over the covered body in a solemn ceremony, according to CCTV.

The comrades took off their helmets and bowed four times in a moment of reverence at the rubble-strewn site, according to footage by China Central Television, the nation’s largest national broadcasting network.

Things could have been even worse if the explosions had come during the day, when more people would have been working in the port area.

The district where the warehouse was located is thinly populated. It’s roughly 40 kilometers (25 miles) from the center of the city, a sprawling metropolis of more than 13 million people. About 90,000 lived within a 5-kilometer radius of the blast site, the China Earthquake Networks Center said.

What to know about the Tianjin crisis

Steven Jiang and Will Ripley reported from Tianjin. Michael Pearson reported and wrote from Atlanta; Michael Martinez from Los Angeles. Kevin Wang, Shen Lu, Elizabeth Joseph, Chieu Luu, Tiffany Ap and Don Melvin also contributed to this report.